WebMar 22, 2024 · The main structural difference between these two complexes is the nature of the exocyclic chalcogen atom, which is a selenium one for [PPh 4][AuSEt(=Se)] and a sulfur one for [PPh 4][AuSEt(=S)].However, the poor water solubility of these complexes, probably related to their planar molecular geometries, constrains their bioavailability, which … WebBimetallic molybdenum dithiolene complexes involving two flexible ditopic conjugated linkers have been synthesized and characterized by electrochemistry, spectroelectrochemistry, …
Synthesis, structure and redox properties of bis(cyclopentadienyl ...
WebA MoIV mono-oxido bis-dithiolene complex, [MoO(mohdt)2]2− (mohdt = 1-methoxy-1-oxo-4-hydroxy-but-2-ene-2,3-bis-thiolate) was synthesized as a structural and functional model for molybdenum oxidoreductase enzymes of the DMSO reductase family. It was comprehensively characterized by inter alia various spectroscopic methods and … Webbis(dithiolene) monoanions in which the dithiolene is electron withdrawing. The Co-S linkages holding the dimer together are longer than the Co-S bond distances in the CoS2C2 chelate rings, whichisconsistentwiththenotionoffacilemonomer-dimerequi-libria in solution (28). Complex 1 was previously reported to be an active catalyst for can autistic people have jobs
Covalent organic frameworks with Ni-Bis(dithiolene) and Co
WebAbstract. [Au (dspdt) 2] (dspdt = 2,3-dihydro-5,6-selenophenedithiolate) is an unprecedented example of a neutral gold bisdithiolene complex with a unique structure composed of … WebTransition metal bisdithiolene complexes based on extended ligands with fused tetrathiafulvalene and thiophene moieties: new single-component molecular metals … WebNov 27, 2007 · Rare electrical conductors: The Au and Ni bisdithiolene complexes (an example of which is shown here) based on new, highly extended ligands that incorporate … can autistic people be geniuses